Fluorescence behaviour of an anthracene-BODIPY system affected by spin states of a dioxolene-cobalt centre.

Abstract

Dioxolene cobalt complexes, [Co(L)(TPA)]PF6 () and [Co(L)(Me3TPA)]PF6 (), were synthesized using a catechol with anthracene and boron-dipyrromethene (BODIPY), H2L, and tris(pyridin-2-ylmethyl)amine (TPA) or tris[(6-methylpyridin-2-yl)methyl]amine (Me3TPA) and characterised by UV-vis absorption, IR and NMR spectroscopy. Complexes and are a low-spin cobalt… (More)
DOI: 10.1039/c6dt00864j

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