Flash Vacuum Pyrolysis of Azides, Triazoles, and Tetrazoles.

@article{Wentrup2017FlashVP,
  title={Flash Vacuum Pyrolysis of Azides, Triazoles, and Tetrazoles.},
  author={C. Wentrup},
  journal={Chemical reviews},
  year={2017},
  volume={117 5},
  pages={
          4562-4623
        }
}
  • C. Wentrup
  • Published 2017
  • Chemistry, Medicine
  • Chemical reviews
Flash vacuum pyrolysis (FVP) of azides is an extremely valuable method of generating nitrenes and studying their thermal rearrangements. The nitrenes can in many cases be isolated in low-temperature matrices and observed spectroscopically. NH and methyl, alkyl, aralkyl, vinyl, cyano, aryl and N-heteroaryl, acyl, carbamoyl, alkoxycarbonyl, imidoyl, boryl, silyl, phosphonyl, and sulfonyl nitrenes are included. FVP of triazoloazines generates diazomethylazines and azinylcarbenes, which often… Expand
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