Five different fluxional processes in polyfluorophenyl palladium(II) complexes with 2,4,6-tris(3,5-dimethylpyrazol-1-yl)-1,3,5-triazine. The driving effect of the solvent.

@article{Carrin2003FiveDF,
  title={Five different fluxional processes in polyfluorophenyl palladium(II) complexes with 2,4,6-tris(3,5-dimethylpyrazol-1-yl)-1,3,5-triazine. The driving effect of the solvent.},
  author={Mar{\'i}a del Carmen Carri{\'o}n and Ana Guerrero and F{\'e}lix A Jal{\'o}n and Blanca R Manzano and Antonio de la Hoz and Rosa M. Claramunt and Viktor Milata and Jos{\'e} Elguero},
  journal={Inorganic chemistry},
  year={2003},
  volume={42 3},
  pages={885-95}
}
The polydentate N-donor ligand 2,4,6-tris(3,5-dimethylpyrazol-1-yl)-1,3,5-triazine (Me(2)-TpzT) has been used to synthesize the new palladium derivatives Pd(R)(2)(Me(2)-TpzT), R = C(6)F(5), 1; R = m-C(6)ClF(4), 2. In the case of complex 2, four different atropisomers have been detected at low temperature. The new complexes exhibit a rich dynamic behavior… CONTINUE READING