Five-coordinate organoaluminum acetylides and crystal structure of the hydrosylate, [Salophen(Bu)Al]2O

Abstract

The first examples of five coordinate aluminum acetylide compounds chelated by a single ligand are reported in this paper. The combination of L(Bu)AlCl (where L1⁄4 Salen (1), Salpen (2), Salophen (3), Salomphen (4)) with LiCBCPh in THF at )78 C leads to the formation of the four acetylides (5–8), LCBCPh. These are extremely moisture sensitive and readily… (More)

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@inproceedings{Wang2004FivecoordinateOA, title={Five-coordinate organoaluminum acetylides and crystal structure of the hydrosylate, [Salophen(Bu)Al]2O}, author={Yuzhong Wang and Sonali Bhandari and Sean R. Parkin and David A. Atwood}, year={2004} }