First magnetostructural study on a heterodinuclear 2,2'-bipyrimidine-bridged complex.

@article{MartnezLillo2011FirstMS,
  title={First magnetostructural study on a heterodinuclear 2,2'-bipyrimidine-bridged complex.},
  author={Jos{\'e} Mart{\'i}nez-Lillo and Donatella Armentano and Giovanni De Munno and Joan Cano and Francesc Lloret and Miguel Julve and Juan Faus},
  journal={Inorganic chemistry},
  year={2011},
  volume={50 24},
  pages={12405-7}
}
The use of the [ReCl(4)(bpym)] precursor as a ligand toward the fully solvated nickel(II) metal ion affords the first example of a 2,2'-bipyrimidine-bridged Re(IV)-Ni(II) complex, [ReCl(4)(μ-bpym)NiBr(2)(H(2)O)(2)] (1), whose intramolecular ferromagnetic coupling has been substantiated from both experimental and theoretical studies. 

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