First catalysis by corrole metal complexes: epoxidation, hydroxylation, and cyclopropanation

@article{Gross1999FirstCB,
  title={First catalysis by corrole metal complexes: epoxidation, hydroxylation, and cyclopropanation},
  author={Z. Gross and L. Simkhovich and N. Galili},
  journal={Chemical Communications},
  year={1999},
  pages={599-600}
}
  • Z. Gross, L. Simkhovich, N. Galili
  • Published 1999
  • Chemistry
  • Chemical Communications
    • The first ever application of corroles shows that their metal complexes are good catalysts, almost as potent as the corresponding metalloporphyrins in the oxygenation of hydrocarbons by iodosylbenzene and superior for the cyclopropanation of olefins by carbenoids. 
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    100 Citations
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    Facile synthesis of a novel sapphyrin and its rhodium(I) complex
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    Bridging and axial carbene binding modes in cobalt corrole complexes: effect on carbene transfer.
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    Iron(IV)-Corrole Catalyzed Stereoselective Olefination of Aldehydes with Ethyl Diazoacetate
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    First synthesis of perfluorinated corrole and its mn=o complex.
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    Mild oxidation of hydrocarbons catalyzed by iron corrole with tert-butylhydroperoxide
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