Ferrocene-based sulfonyl dihydropyrazole derivatives: Synthesis, structure, electrochemistry and effect on thermal decomposition of NH4ClO4

@article{Zhuo2014FerrocenebasedSD,
  title={Ferrocene-based sulfonyl dihydropyrazole derivatives: Synthesis, structure, electrochemistry and effect on thermal decomposition of NH4ClO4},
  author={Ji-Bin Zhuo and Heng-dong Li and Cai-Xia Lin and Li-Li Xie and Sha Bai and Yaofeng Yuan},
  journal={Journal of Molecular Structure},
  year={2014},
  volume={1067},
  pages={112-119}
}
Abstract Three ferrocene-based sulfonyl-substituted dihydropyrazoles 3a–c have been synthesized, from the corresponding α,β-unsaturated diketones, and fully characterized. The crystal structures of 3a–c have been confirmed by X-ray crystallography, and electrochemistry behaviors of 3a–c have been examined by cyclic voltammetry (CV). Representatively, the mechanism of the electron transfer in redox process of 3a has been verified by density functional theory (DFT) calculation. It has been found… Expand
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