Fast CO2 hydration kinetics impair heterogeneous but improve enzymatic CO2 reduction catalysis

@article{Cobb2022FastCH,
  title={Fast CO2 hydration kinetics impair heterogeneous but improve enzymatic CO2 reduction catalysis},
  author={Samuel J. Cobb and Vivek Badiani and Azim M. Dharani and Andreas Wagner and S{\'o}nia Zacarias and Ana Rita Oliveira and In{\^e}s A. C. Pereira and Erwin Reisner},
  journal={Nature Chemistry},
  year={2022},
  volume={14},
  pages={417 - 424}
}
The performance of heterogeneous catalysts for electrocatalytic CO2 reduction suffers from unwanted side reactions and kinetic inefficiencies at the required large overpotential. However, immobilized CO2 reduction enzymes—such as formate dehydrogenase—can operate with high turnover and selectivity at a minimal overpotential and are therefore ‘ideal’ model catalysts. Here, through the co-immobilization of carbonic anhydrase, we study the effect of CO2 hydration on the local environment and… 

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