Faradaic double layer depolarization in electrokinetics: Onsager relations and substrate limitations.


More often than not, the measurement of interfacial potentials by means of electrokinetic techniques is affected by interfering processes that may relax or even annihilate their primary response function. Among these processes are faradaic ones, provided that the substrate is sufficiently conducting and a redox function is available, and non-faradaic ones… (More)


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