Facile synthesis of hydrotalcite and its thermal decomposition kinetics mechanism study with masterplots method

@article{Long2014FacileSO,
  title={Facile synthesis of hydrotalcite and its thermal decomposition kinetics mechanism study with masterplots method},
  author={Qiwei Long and Yao Xia and Sen Liao and Y. Li and Wenwei Wu and Yingheng Huang},
  journal={Thermochimica Acta},
  year={2014},
  volume={579},
  pages={50-55}
}
Abstract The hydrotalcite, Mg4Al2(OH)12CO3·3H2O, was synthesized via low-heating solid-state reaction at 80 °C. The thermal decomposition of Mg4Al2(OH)12CO3·3H2O experienced two stages. The apparent activation energy Ea was estimated with Vyazovkin procedure. The average values of Ea associated with the two stages were determined to be 110.9 ± 10.3, 140.3 ± 4.2 kJ mol−1, respectively, which the two stages are single-step kinetic processes. Masterplots and nonlinear methods were used to define… Expand
Synthesis and isoconversional kinetic study of the formation of LiNiPO4 from Ni3(PO4)2·8H2O as a new precursor
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