Facile synthesis of WS2 nanotubes by sulfurization of tungsten thin films: formation mechanism, and structural and optical properties.

@article{Hossain2018FacileSO,
  title={Facile synthesis of WS2 nanotubes by sulfurization of tungsten thin films: formation mechanism, and structural and optical properties.},
  author={Emroj Hossain and A. A. Rahman and Rudheer D. Bapat and Jayesh B. Parmar and Amit P. Shah and Ashish Arora and Rudolf Bratschitsch and Arnab Bhattacharya},
  journal={Nanoscale},
  year={2018},
  volume={10 35},
  pages={
          16683-16691
        }
}
While 2D layers of WS2 have been extensively studied, there are very few investigations of WS2 nanotubes. These have usually been grown via a 2-step process involving a WO3-x intermediate. We report a simple process for the synthesis of WS2 nanotubes via the sulfurization of tungsten films under appropriate conditions and present details of their structural and optical properties that help elucidate the formation mechanism. Electron-beam evaporated films of tungsten are sulfurized under flowing… 
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References

SHOWING 1-10 OF 35 REFERENCES
Study of the growth mechanism of WS2 nanotubes produced by a fluidized bed reactor
Metal dichalcogenide nanotubes and in particular those of WS2 were shown to exhibit some unique physical and chemical properties, which offer numerous applications for this kind of nanophase
Synthesis of Large-Area WS2 monolayers with Exceptional Photoluminescence
TLDR
It is demonstrated that the introduction of hydrogen to the argon carrier gas dramatically improves the optical quality and increases the growth area of WS2, resulting in films exhibiting mm2 coverage.
The optical response of monolayer, few-layer and bulk tungsten disulfide.
TLDR
It is shown that the optical band-gap absorption of monolayer WS2 is governed by competing resonances arising from one neutral and two distinct negatively charged excitons whose contributions to the overall absorption of light vary as a function of temperature and carrier concentration.
Direct chemical vapor deposition growth of WS2 atomic layers on hexagonal boron nitride.
TLDR
Direct chemical vapor deposition (CVD) growth of WS2 onto high-quality hBN using a 3-furnace CVD setup is reported, indicating the high quality of the present WS2 atomic layers with high crystallinity and clean interface.
Structures of exfoliated single layers of WS 2 , MoS 2 , and MoSe 2 in aqueous suspension
Single layers of the transition-metal dichalcogenides WS 2 , MoS 2 , and MoSe 2 were formed as aqueous suspensions by lithium intercalation and exfoliation of crystalline powders and examined by
Electronic structure of atomically resolved carbon nanotubes
Carbon nanotubes can be thought of as graphitic sheets with a hexagonal lattice that have been wrapped up into a seamless cylinder. Since their discovery in 1991, the peculiar electronic properties
Excitonic resonances in thin films of WSe2: from monolayer to bulk material.
We present optical spectroscopy (photoluminescence and reflectance) studies of thin layers of the transition metal dichalcogenide WSe2, with thickness ranging from mono- to tetra-layer and in the
Growth of WS2 Nanotubes Phases
Recently, a method to produce bulk quantities of pure multiwall WS2 nanotubes, which could reach several microns in length, has been developed. A detailed study of the growth mechanism of these WS2
Electronics and optoelectronics of two-dimensional transition metal dichalcogenides.
TLDR
This work reviews the historical development of Transition metal dichalcogenides, methods for preparing atomically thin layers, their electronic and optical properties, and prospects for future advances in electronics and optoelectronics.
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