Fabrication of ZIF-8@SiO2 core-shell microspheres as the stationary phase for high-performance liquid chromatography.

@article{Fu2013FabricationOZ,
  title={Fabrication of ZIF-8@SiO2 core-shell microspheres as the stationary phase for high-performance liquid chromatography.},
  author={Yan-Yan Fu and Cheng-Xiong Yang and Xiu-Ping Yan},
  journal={Chemistry},
  year={2013},
  volume={19 40},
  pages={13484-91}
}
The unique features of high porosity, shape selectivity, and multiple active sites make metal-organic frameworks (MOFs) promising as novel stationary phases for high-performance liquid chromatography (HPLC). However, the wide particle size distribution and irregular shape of conventional MOFs lead to lower column efficiency of such MOF-packed columns. Herein, the fabrication of monodisperse MOF@SiO2 core-shell microspheres as the stationary phase for HPLC to overcome the above-mentioned… CONTINUE READING
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