Fabrication and Morphological Characterization of High-Efficiency Blade-Coated Perovskite Solar Modules.

@article{Matteocci2019FabricationAM,
  title={Fabrication and Morphological Characterization of High-Efficiency Blade-Coated Perovskite Solar Modules.},
  author={Fabio Matteocci and Luigi Vesce and Felix Utama Kosasih and Luigi Angelo Castriotta and Stefania Cacovich and Alessandro Lorenzo Palma and Giorgio Divitini and Caterina Ducati and Aldo Di Carlo},
  journal={ACS applied materials \& interfaces},
  year={2019}
}
Organo-metal halide perovskite demonstrates a large potential for achieving highly efficient photovoltaic devices. The scaling-up process represents one of the major challenges to exploit this technology at the industrial level. Here, the scaling-up of perovskite solar modules from 5 × 5 to 10 × 10 cm2 substrate area is reported by blade coating both the CH3NH3PbI3 perovskite and spiro-OMeTAD layers. The sequential deposition approach is used in which both lead iodide (PbI2) deposition and the… 
Two-step sequential blade-coating of high quality perovskite layers for efficient solar cells and modules
Although perovskite solar cells have achieved an efficiency over 25%, the scalable fabrication of high efficiency and stable large perovskite solar modules is still a big challenge. To date, various
Efficient triple-mesoscopic perovskite solar mini-modules fabricated with slot-die coating
Abstract Triple-mesoscopic perovskite solar cells (PSCs) based on the architecture of TiO2/ZrO2/Carbon have attracted much attention due to the high stability and simple fabrication process. The
Progress in blade-coating method for perovskite solar cells toward commercialization
The hybrid organic–inorganic halide perovskite solar cells (PSCs) have attracted considerable attention in the photovoltaic community during the last decade due to unique properties, such as high
Efficient and Stable Perovskite Large Area Cells by Low-Cost Fluorene-Xantene-Based Hole Transporting Layer
Among the new generation photovoltaics, perovskite solar cell (PSC) technology reached top efficiencies in a few years. Currently, the main objective to further develop PSCs is related to the
Low temperature process of homogeneous and pinhole free Perovskite layers for fully coated photovoltaic devices up to 256 cm2 area at ambient condition
The versatility of printing/coating technologies together with the development of new hybrid and organic materials permit to revolutionize the photovoltaic (PV) research and manufacture. Among the
Easy strategy to enhance thermal stability of planar PSCs by perovskite defect passivation and low-temperature carbon-based electrode.
TLDR
A detailed study on thermal and moisture stability of large area (1 cm2) LT planar PSCs is presented and the key role on thermal stability of potassium iodide (KI) insertion in the perovskite composition is demonstrated.
Large-area perovskite films for PV applications: A perspective from nucleation and crystallization
Abstract Perovskite solar cells (PSCs) have attracted significant research interest due to the rapid rise in efficiency. However, a large efficiency gap still exists between laboratory-based small
Upscaling Inverted Perovskite Solar Cells: Optimization of Laser Scribing for Highly Efficient Mini-Modules
TLDR
This work demonstrates for the first time the interconnection of inverted modules with NiOx using a UV ns laser, obtaining a 10.2 cm2 minimodule with a 15.9% efficiency on the active area, the highest for a NiOx based perovskite module.
Light-Stable Methylammonium-Free Inverted Flexible Perovskite Solar Modules on PET Exceeding 10.5% on a 15.7 cm2 Active Area
TLDR
This work demonstrates an outstanding light stability of FPSMs over 1000 h considering the recovering time, exhibiting a power conversion efficiency of 10.51% over a 15.7 cm2 active area obtained with scalable processes by exploiting blade deposition of a transporting layer and a stable double-cation perovskite absorber.
Stability Assessment of p-i-n Perovskite Photovoltaic Mini-Modules Utilizing Different Top Metal Electrodes
TLDR
This work demonstrates the fabrication of fully laser-patterned series interconnected p-i-n perovskite mini- modules, in which either single Cu or Ag layers are compared with Cu/Au metal-bilayer top electrodes, and highlights the importance of optimizing the top-contact composition to tackle the operational stability of mini-modules.
...
1
2
3
4
...

References

SHOWING 1-10 OF 79 REFERENCES
A crystal engineering approach for scalable perovskite solar cells and module fabrication: a full out of glove box procedure
In the present work we used some crystallization trends which could be classified as a Crystal Engineering (CE) approach, for deposition of a pure cubic-phase thin film of CH3NH3PbI3 (MAPbI3) on the
Enhanced efficiency of planar perovskite solar cells via a two-step deposition using DMF as an additive to optimize the crystal growth behavior
The performance of perovskite solar cells (PSCs) is extremely dependent on the morphology and crystallization of the perovskite film. However, the complete conversion of PbI2 to perovskite and
Fast two-step deposition of perovskite via mediator extraction treatment for large-area, high-performance perovskite solar cells
As the efficiency of perovskite solar cells (PSCs) reached more than 22%, the large-area fabrication of PSCs became another issue receiving growing attention. For large-area PSCs, more
Perovskite solar cells and large area modules (100 cm2) based on an air flow-assisted PbI2 blade coating deposition process
The present work focuses on research into alternative and more scalable processes for organometal halide perovskite layer deposition. We compare solar cells fabricated by sequential step deposition
Porous PbI2 films for the fabrication of efficient, stable perovskite solar cells via sequential deposition
Two-step sequential deposition has been widely used for the fabrication of organolead halide perovskites due to its efficient pore-filling in mesostructured perovskite solar cells (PSCs) and great
Enhanced Environmental Stability of Planar Heterojunction Perovskite Solar Cells Based on Blade‐Coating
DOI: 10.1002/aenm.201401229 that the blade-coating process encourages the formation of self-assembled large perovskite crystalline domains featuring uniform fi lm coverage and signifi cantly improved
Low-Temperature Presynthesized Crystalline Tin Oxide for Efficient Flexible Perovskite Solar Cells and Modules.
TLDR
This work presents a facile low-temperature synthesis of crystalline SnO2 nanocrystals (NCs) as efficient ETLs for flexible PSCs including modules and shows promising for future manufacturing.
Sequential deposition as a route to high-performance perovskite-sensitized solar cells
TLDR
A sequential deposition method for the formation of the perovskite pigment within the porous metal oxide film that greatly increases the reproducibility of their performance and allows the fabrication of solid-state mesoscopic solar cells with unprecedented power conversion efficiencies and high stability.
Improved performance and stability of perovskite solar cells by crystal crosslinking with alkylphosphonic acid ω-ammonium chlorides.
TLDR
A one-step solution-processing strategy using phosphonic acid ammonium additives that results in efficient perovskite solar cells with enhanced stability, enhancing the material's photovoltaic performance from 8.8 to 16.7% as well as its resistance to moisture.
Controllable Perovskite Crystallization by Water Additive for High-Performance Solar Cells
A key issue for perovskite solar cells is the stability of perovskite materials due to moisture effects under ambient conditions, although their efficiency is improved constantly. Herein, an improved
...
1
2
3
4
5
...