Extreme population inversion in the fragments formed by UV photoinduced S-H bond fission in 2-thiophenethiol.


H atom loss following near ultraviolet photoexcitation of gas phase 2-thiophenethiol molecules has been studied experimentally, by photofragment translational spectroscopy (PTS) methods, and computationally, by ab initio electronic structure calculations. The long wavelength (277.5 ≥ λ(phot) ≥ 240 nm) PTS data are consistent with S-H bond fission after… (More)
DOI: 10.1039/c6cp01593j


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