Exploring the possibilities of two-dimensional transition metal carbides as anode materials for sodium batteries.

@article{Yang2015ExploringTP,
  title={Exploring the possibilities of two-dimensional transition metal carbides as anode materials for sodium batteries.},
  author={Eunjeong Yang and Hyunjun Ji and Jaehoon Kim and Heejin Kim and Yousung Jung},
  journal={Physical chemistry chemical physics : PCCP},
  year={2015},
  volume={17 7},
  pages={
          5000-5
        }
}
Recently a group of two-dimensional materials called MXenes have been discovered and they have demonstrated their potential in Li rechargeable batteries. Herein, the Na storage and ion migration properties of M2C-type MXenes (M = Ti, V, Cr, Mn, Fe, Co, Ni, Nb, Mo) were investigated using density functional theory (DFT) calculations, and were compared to the Li case. Based on the average voltage and migration barrier of surface ions, we suggest that M = Ti, V, Cr, Mn, and Mo are suitable for… 

Two-dimensional MnC as a potential anode material for Na/K-ion batteries: a theoretical study

Monolayer MnC monolayer absorbed with two layers of Na atoms can be a promising anode material for NIBs and KIBs.

A Mini-Review: MXene composites for sodium/potassium-ion batteries.

Building composite materials with MXenes can not only improve the capacity but also enhance the electronic conductivity of the materials, effectively alleviate volume expansion in the reaction process, and achieve better electrochemical performance.

Blue-AsP monolayer as a promising anode material for lithium- and sodium-ion batteries: a DFT study.

A one two-dimensional (2D) blue AsP (b-AsP) monolayer is proposed as an ideal anode material for lithium/sodium-ion (Li/Na-ion) batteries for the first time and possesses thermal and dynamic stabilities.

MXenes for Non‐Lithium‐Ion (Na, K, Ca, Mg, and Al) Batteries and Supercapacitors

The 2019 Nobel Prize in Chemistry for lithium‐ion batteries is a powerful confirmation of the importance of portable energy storage devices, which will further promote collaborative innovation in the
...

References

SHOWING 1-10 OF 48 REFERENCES

Cation Intercalation and High Volumetric Capacitance of Two-Dimensional Titanium Carbide

This study demonstrates the spontaneous intercalation of cations from aqueous salt solutions between two-dimensional (2D) Ti3C2 MXene layers, and provides a basis for exploring a large family of 2D carbides and carbonitrides in electrochemical energy storage applications using single- and multivalent ions.

Are MXenes promising anode materials for Li ion batteries? Computational studies on electronic properties and Li storage capability of Ti3C2 and Ti3C2X2 (X = F, OH) monolayer.

The exceptional properties, including good electronic conductivity, fast Li diffusion, low operating voltage, and high theoretical Li storage capacity, make Ti(3)C(2) MXene a promising anode material for Li ion batteries.

Role of surface structure on Li-ion energy storage capacity of two-dimensional transition-metal carbides.

L lithiated oxygen terminated MXenes surfaces are able to adsorb additional Li beyond a monolayer, providing a mechanism to substantially increase capacity, as observed mainly in delaminated MXenes and confirmed by DFT calculations and XAS.

Sodium ion insertion in hollow carbon nanowires for battery applications.

Hollow carbon nanowires prepared through pyrolyzation of a hollow polyaniline nanowire precursor deliver high reversible capacity and excellent cycling stability and the good Na-ion insertion property is attributed to the short diffusion distance in the HCNWs and the large interlayer distance.

Electrode Materials for Rechargeable Sodium‐Ion Batteries: Potential Alternatives to Current Lithium‐Ion Batteries

Lithium (Li)‐ion batteries (LIB) have governed the current worldwide rechargeable battery market due to their outstanding energy and power capability. In particular, the LIB's role in enabling

Sodium‐Ion Batteries

The status of ambient temperature sodium ion batteries is reviewed in light of recent developments in anode, electrolyte and cathode materials. These devices, although early in their stage of

Intrinsic thermodynamic and kinetic properties of Sb electrodes for Li-ion and Na-ion batteries: experiment and theory

A detailed comparative study between the electrochemical lithiation and sodiation of pure antimony (Sb), relating changes in structural, thermodynamic, kinetic and electrochemical properties has been

NiCo2O4 Spinel: First Report on a Transition Metal Oxide for the Negative Electrode of Sodium-Ion Batteries

This is the first time that a mixed transition metal oxide is used for the negative electrode of a sodium-ion battery. The NiCo2O4 spinel was prepared by thermal decomposition of oxalate precursors

Novel Electronic and Magnetic Properties of Two‐Dimensional Transition Metal Carbides and Nitrides

Layered MAX phases are exfoliated into 2D single layers and multilayers, so‐called MXenes. Using first‐principles calculations, the formation and electronic properties of various MXene systems, M2C