Experimental and theoretical investigations of new dinuclear palladium complexes as precatalysts for the amination of aryl chlorides.


A series of new palladium dinuclear species with general formula [Pd2X(mu-X)[mu-P(t)Bu2(Bph-R)]] (X = Cl, Br; Bph = biphenyl; R = H, Me, NMe2) have been prepared. The two palladium centers in these species are bridged by one of the aromatic rings of the biphenyl group present in the corresponding phosphine. The X-ray crystal structure of one of these… (More)


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