Experimental and theoretical investigations of lithium and magnesium derivatives of bis(tert-butylamido)cyclodiphosph(III/V)- and (V/V)azane mono- and ditellurides.

Abstract

Deprotonation of bis(tert-butylamido)cyclophosph(III/III)azane with organolithium or organomagnesium reagents followed by oxidation with elemental tellurium is a viable approach to the preparation of metal cyclodiphosphazane mono- and ditellurides. The reaction of the cyclodiphosph(III)azane [tBu(H)NP(mu-NtBu)2PN(H)tBu] (1) with elemental tellurium in… (More)

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