Experimental and theoretical determinations of bond lengths in naphthalene, anthracene and other hydrocarbons

  title={Experimental and theoretical determinations of bond lengths in naphthalene, anthracene and other hydrocarbons},
  author={D. Cruickshank and R. Sparks},
  journal={Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences},
  pages={270 - 285}
  • D. Cruickshank, R. Sparks
  • Published 1960
  • Chemistry
  • Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences
Recent independent determinations by X-ray crystallography of the C—C bond lengths in naphthalene and anthracene are shown to agree well. The experimental values agree to about 0-01 Å with both the simple molecular orbital and simple Pauling theories. These theories also make satisfactory predictions for 1.2 : 8.9-dibenzacridine and chrysene (except for the bond most affected by steric hindrance). The agreement between the two theories for aromatic molecules is traced to a correlation of their… Expand

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