Experimental and DFT evidence for the fractional non-innocence of a β-diketonate ligand.

Abstract

New compounds [Ru(pap)(2)(L)](ClO(4)), [Ru(pap)(L)(2)], and [Ru(acac)(2)(L)] (pap = 2-phenylazopyridine, L(-) = 9-oxidophenalenone, acac(-) = 2,4-pentanedionate) have been prepared and studied regarding their electron-transfer behavior, both experimentally and by using DFT calculations. [Ru(pap)(2)(L)](ClO(4)) and [Ru(acac)(2)(L)] were characterized by… (More)
DOI: 10.1002/chem.201201785

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