Experimental and Computational Assessment of Reactivity and Mechanism in C(sp(3))-N Bond-Forming Reductive Elimination from Palladium(IV).

Abstract

This report describes a combined experimental and computational investigation of the mechanism of C(sp(3))-N bond-forming reductive elimination from sulfonamide-ligated Pd(IV) complexes. After an initial experimental assessment of reactivity, we used ZStruct, a computational combinatorial reaction finding method, to analyze a large number of multistep… (More)
DOI: 10.1021/jacs.6b02714

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Cite this paper

@article{Pendleton2016ExperimentalAC, title={Experimental and Computational Assessment of Reactivity and Mechanism in C(sp(3))-N Bond-Forming Reductive Elimination from Palladium(IV).}, author={Ian M Pendleton and M{\'o}nica H P{\'e}rez-Temprano and Melanie S Sanford and Paul M. Zimmerman}, journal={Journal of the American Chemical Society}, year={2016}, volume={138 18}, pages={6049-60} }