Experimental Demonstration of an Electride as a 2D Material.
@article{Druffel2016ExperimentalDO, title={Experimental Demonstration of an Electride as a 2D Material.}, author={Daniel L. Druffel and Kaci L. Kuntz and Adam H. Woomer and F. M. Alcorn and Jun Hu and Carrie L. Donley and Scott C. Warren}, journal={Journal of the American Chemical Society}, year={2016}, volume={138 49}, pages={ 16089-16094 } }
Because of their loosely bound electrons, electrides offer physical properties useful in chemical synthesis and electronics. For these applications and others, nanosized electrides offer advantages, but to-date no electride has been synthesized as a nanomaterial. We demonstrate experimentally that Ca2N, a layered electride in which layers of atoms are separated by layers of a 2D electron gas (2DEG), can be exfoliated into two-dimensional (2D) nanosheets using liquid exfoliation. The 2D flakes…
94 Citations
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