Exotic Protonated Species Produced by UV-Induced Photofragmentation of a Protonated Dimer: Metastable Protonated Cinchonidine.

Abstract

A metastable protonated cinchona alkaloid was produced in the gas phase by UV-induced photodissociation (UVPD) of its protonated dimer in a Paul ion trap. The infrared multiple photon dissociation (IRMPD) spectrum of the molecular ion formed by UVPD was obtained and compared to DFT calculations to characterize its structure. The protonation site obtained… (More)
DOI: 10.1021/acs.jpca.5b06506

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Cite this paper

@article{Alata2015ExoticPS, title={Exotic Protonated Species Produced by UV-Induced Photofragmentation of a Protonated Dimer: Metastable Protonated Cinchonidine.}, author={Ivan Alata and Debora Scuderi and Val{\'e}ria Lep{\`e}re and Vincent Steinmetz and Fabrice Gobert and Lo{\"{i}c Thiao-Layel and Katia Le Barbu-Debus and Anne Zehnacker-Rentien}, journal={The journal of physical chemistry. A}, year={2015}, volume={119 39}, pages={10007-15} }