Existence of Diabatic Potentials and the Quantization of the Nonadiabatic Matrix

@inproceedings{Baer2000ExistenceOD,
  title={Existence of Diabatic Potentials and the Quantization of the Nonadiabatic Matrix},
  author={Michael Baer and Soreq Nrc},
  year={2000}
}
In this work are considered nonadiabatic matrices which were not derived from first principles. For this type of nonadiabatic matrices we derived the conditions for such an N × N matrix to yield an N × N diabatic potential matrix which is continuous throughout configuration space. It is shown that these conditions are very close to being quantization type conditions which select from all possible matrices only a certain group. The final theoretical results are supported by examples (a) for the… CONTINUE READING

References

Publications referenced by this paper.

One ( less important ) exceptional case will be discussed elsewhere

A Alijah, M. Baer
  • J . Phys . Chem . A
  • 2000