Excited state non-adiabatic dynamics of the smallest polyene, trans 1,3-butadiene. I. Time-resolved photoelectron-photoion coincidence spectroscopy.

@article{Boguslavskiy2018ExcitedSN,
  title={Excited state non-adiabatic dynamics of the smallest polyene, trans 1,3-butadiene. I. Time-resolved photoelectron-photoion coincidence spectroscopy.},
  author={Andrey Boguslavskiy and Oliver Schalk and Niklas Gador and William J Glover and Toshifumi Mori and Thomas Schultz and Michael S. Schuurman and Todd J. Mart{\'i}nez and Albert Stolow},
  journal={The Journal of chemical physics},
  year={2018},
  volume={148 16},
  pages={
          164302
        }
}
The ultrafast excited state dynamics of the smallest polyene, trans-1,3-butadiene, were studied by femtosecond time-resolved photoelectron-photoion coincidence (TRPEPICO) spectroscopy. The evolution of the excited state wavepacket, created by pumping the bright 1Bu (ππ*) electronic state at its origin of 216 nm, is projected via one- and two-photon… CONTINUE READING