Evolution of organo-cyanometallate cages: supramolecular architectures and new Cs+-specific receptors.

@article{Boyer2007EvolutionOO,
  title={Evolution of organo-cyanometallate cages: supramolecular architectures and new Cs+-specific receptors.},
  author={Julie L Boyer and Matthew L. Kuhlman and Thomas B Rauchfuss},
  journal={Accounts of chemical research},
  year={2007},
  volume={40 4},
  pages={233-42}
}
The ability of inorganic cyanometallate polymers to form interesting and useful complexes is well-known. This Account summarizes work, especially in our laboratories, aimed at replicating aspects of this inorganic chemistry in homogeneous solution using organometallic building blocks. A library of molecular organometallic cyanides and Lewis acids, with… CONTINUE READING