Evidence of photoinduced charge separation in the metal-organic framework MIL-125(Ti)-NH2.

Abstract

Herein, we describe the photochemical behavior of the porous metal-organic framework MIL-125(Ti)-NH(2), built up from cyclic Ti(8)O(8)(OH)(4) oxoclusters and 2-aminoterephthalate ligands. While MIL-125(Ti)-NH(2) does not emit upon excitation at 420 nm, laser flash photolyses of dry samples (diffuse reflectance) or aqueous suspensions (transmission) of the… (More)
DOI: 10.1002/cphc.201200411

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@article{Miguel2012EvidenceOP, title={Evidence of photoinduced charge separation in the metal-organic framework MIL-125(Ti)-NH2.}, author={Maykel de Miguel and Florence Ragon and Thomas Devic and Christian Serre and Patricia Horcajada and Hermenegildo Garc{\'i}a}, journal={Chemphyschem : a European journal of chemical physics and physical chemistry}, year={2012}, volume={13 16}, pages={3651-4} }