Evidence of an equilibrium between selenides and osmium(VIII) reagents and selenoxides and osmium(VI) reagents.

Abstract

Driving the equilibrium between selenides and osmium(VIII) reagents with selenoxides and osmium(VI) by a subsequent reaction (rearrangement of allyl selenoxides to allyl alcohols or addition of osmium(VIII) species on C=C double bonds) to one side, allows the transformation of methyl geranyl selenides to linalool and of methyl citronellyl selenoxide to 6,7… (More)

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@article{Krief2002EvidenceOA, title={Evidence of an equilibrium between selenides and osmium(VIII) reagents and selenoxides and osmium(VI) reagents.}, author={Alain Krief and Alexandra Destree and Virginie Durisotti and Nicolas Moreau and Caroline Smal and Catherine Colaux-Castillo}, journal={Chemical communications}, year={2002}, volume={6}, pages={558-9} }