Evidence for a "carbene-like" intermediate during the reaction of methoxy species with light alkenes on H-ZSM-5.

Abstract

There have been various discussions of the mechanism of methanol to olefin (MTO) and methanol to hydrocarbon (MTHC) reactions specifically dealing with certain zeolite topologies of CHA, MFI, BEA, TON, and others, as well as general summaries. One example of particular interest is the structure of hydrocarbons formed in zeolite channels, the so-called… (More)
DOI: 10.1002/anie.201007178

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