Even-odd product variation of the C(n)(+) + D(2) (n = 4-9) reaction: complexity of the linear carbon cation electronic states.

Abstract

We have studied reactions between linear Cn(+) (n = 4-9) and D2, using ion mobility mass spectrometry techniques and quantum chemical calculations in order to understand the complex reactivity of the linear cluster cations. Only linear CnD(+) products were observed for the odd (n = 5, 7, 9) linear clusters, while CnD2(+) was the main product for the even… (More)
DOI: 10.1039/c5cp04480d

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