Evaluation of intrinsic chemical kinetics and transient product spectra from time-resolved spectroscopic data.

@article{Dioumaev1997EvaluationOI,
  title={Evaluation of intrinsic chemical kinetics and transient product spectra from time-resolved spectroscopic data.},
  author={Andrei K. Dioumaev},
  journal={Biophysical chemistry},
  year={1997},
  volume={67 1-3},
  pages={1-25}
}
This communication is devoted to the evaluation of true spectra and intrinsic (microscopic) rate constants from apparent kinetics measured in time-resolved spectroscopic experiments monitoring complex relaxation dynamics of multi-intermediate systems. Retinal proteins, cytochrom c oxidase, phytochrome, hemoglobin, and photoactive yellow protein are examples of natural systems in which several transient states (intermediates) overlap so strongly, both in time and spectral domains, that their… CONTINUE READING

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