Evaluation of Methylthio and Phenylthio Group Effects in the Solvolyses of 2-Chloro-2-(methylthio)acetone and 2-Chloro-2-(phenylthio)acetophenone Using Extended Grunwald-Winstein Equations

@article{Ryu2008EvaluationOM,
  title={Evaluation of Methylthio and Phenylthio Group Effects in the Solvolyses of 2-Chloro-2-(methylthio)acetone and 2-Chloro-2-(phenylthio)acetophenone Using Extended Grunwald-Winstein Equations},
  author={Z. H. Ryu and T. Bentley},
  journal={Bulletin of The Korean Chemical Society},
  year={2008},
  volume={29},
  pages={2145-2151}
}
  • Z. H. Ryu, T. Bentley
  • Published 2008
  • Chemistry
  • Bulletin of The Korean Chemical Society
  • C have been measured in more than 34 aqueous solvent mixturesincluding aqueous 2,2,2-trifluoroethanol (TFE), for 4, and 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP), and inTFE-ethanol. The kinetic solvent isotope effect in methanol and solvolysis rate ratios, at identical ionizingpower in 40 (v/v)% ethanol/water compared with 97 (w/w)% TFE/water have been determined. Additional datawere also obtained for solvolyses of other substrates related to this work. The investigation of structural effects… CONTINUE READING
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