Eu(III) emission band changes caused by peripheral C-H/O hydrogen bonding.

Abstract

We synthesized Eu(III) and Sm(III) complexes with tridentate phosphine oxide ligands, Eu(hfa)(3)(TPPM) and Sm(hfa)(3)(TPPM) (hfa: hexafluoroacetylacetonato, TPPM: tris(diphenylphosphinyl)methane), and we then examined their luminescent properties. In the complexes the Eu(III) and Sm(III) centres were fully surrounded by low-vibrational frequency ligands… (More)
DOI: 10.1039/c2dt30538k

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Cite this paper

@article{Kuramochi2012EuIIIEB, title={Eu(III) emission band changes caused by peripheral C-H/O hydrogen bonding.}, author={Yusuke Kuramochi and Tetsuya Nakagawa and Toshiaki Yokoo and Junpei Yuasa and Tsuyoshi Kawai and Yasuchika Hasegawa}, journal={Dalton transactions}, year={2012}, volume={41 22}, pages={6634-40} }