Estimation of kinetic parameters when modifiers are bound in enzyme-catalyzed reactions.

@article{Alberty2010EstimationOK,
  title={Estimation of kinetic parameters when modifiers are bound in enzyme-catalyzed reactions.},
  author={Robert A. Alberty},
  journal={The journal of physical chemistry. B},
  year={2010},
  volume={114 4},
  pages={1684-9}
}
Modifiers of enzyme-catalyzed reactions can have various types of effects on the velocity, but the most important effect is that they provide multiple pathways to products. The rapid-equilibrium kinetic effects of modifiers are explored for the enzyme-catalyzed reaction A --> products. When a single molecule of modifier X is bound, the mechanism involves three independent equilibrium expressions and two rate constants. But when two molecules of X are bound are bound in two reactions, there are… CONTINUE READING

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