Estimation of σ-Donation and π-Backdonation of Cyclic Alkyl(amino) Carbene-Containing Compounds.

@article{Mondal2016EstimationO,
  title={Estimation of σ-Donation and π-Backdonation of Cyclic Alkyl(amino) Carbene-Containing Compounds.},
  author={Kartik Chandra Mondal and Sudipta Mukhopadhyay Roy and Bholanath Maity and Debasis Koley and Herbert W Roesky},
  journal={Inorganic chemistry},
  year={2016},
  volume={55 1},
  pages={163-9}
}
Herein, we present a general method for a reliable estimation of the extent of π-backdonation (CcAAC←E) of the bonded element (E) to the carbene carbon atom and CcAAC→E σ-donation. The CcAAC←E π-backdonation has a significant effect on the electronic environments of the (15)N nucleus. The estimation of the π-backdonation has been achieved by recording the chemical shift values of the (15)N nuclei via two-dimensional heteronuclear multiple-bond correlation spectroscopy. The chemical shift values… CONTINUE READING

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