Epitaxial growth of heterogeneous metal nanocrystals: from gold nano-octahedra to palladium and silver nanocubes.

@article{Fan2008EpitaxialGO,
  title={Epitaxial growth of heterogeneous metal nanocrystals: from gold nano-octahedra to palladium and silver nanocubes.},
  author={Feng-Ru Fan and De-Yu Liu and Yicheng Wu and Sai Duan and Zhao-xiong Xie and Zhi-yuan Jiang and Zhong-Qun Tian},
  journal={Journal of the American Chemical Society},
  year={2008},
  volume={130 22},
  pages={
          6949-51
        }
}
With octahedral Au nanocrystals as seeds, highly monodisperse Au@Pd and Au@Ag core-shell nanocubes were synthesized by a two-step seed-mediated method in aqueous solution. Accordingly, we have preliminarily proposed a general rule that the atomic radius, bond dissociation energy, and electronegativity of the core and shell metals play key roles in determining the conformal epitaxial layered growth mode. 
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