Enzymatic monoesterification of symmetric diols: restriction of molecular conformations influences selectivity.

Abstract

We have experimentally demonstrated that by 'locking' the molecular conformation through the introduction of a double or triple bond in the center of a symmetric diol, enzymatic monoesterification can be achieved selectively. The enzyme Candida antarctica lipase B, generally used for the transesterification of diols, can be effectively used for the… (More)
DOI: 10.1039/c7ob01951c

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