## Signatures of Solvation Thermodynamics in Spectra of Intermolecular Vibrations

- Rasmus A X Persson, Viren Pattni, Anurag Singh, Stefan M Kast, Matthias Heyden
- Journal of chemical theory and computation
- 2017

@article{Keyes2000EntropyDA, title={Entropy, dynamics, and instantaneous normal modes in a random energy model}, author={Keyes}, journal={Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics}, year={2000}, volume={62 6 Pt A}, pages={7905-8} }

- Published 2000 in Physical review. E, Statistical physics, plasmas…

It is shown that the fraction f(u) of imaginary-frequency instantaneous normal modes (INM) may be defined and calculated in a random energy model (REM) of liquids. The configurational entropy S(c) and the averaged hopping rate among the states, R, are also obtained and related to f(u) with the results R approximately f(u) and S(c)=a+b ln(f(u)). The… CONTINUE READING

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