Entrapment of a chiral cobalt complex within silver: a novel heterogeneous catalyst for asymmetric carboxylation of benzyl bromides with CO2.

Abstract

A novel way to accommodate heterogeneous catalysis, CO2 fixation and asymmetric synthesis on one catalyst is reported. The [Co]@Ag composite was prepared for the first time and used for asymmetric carboxylation of benzyl bromides with CO2. All the procedures were performed under mild conditions. Moreover, the [Co]@Ag composite has terrific stability and… (More)
DOI: 10.1039/c5cc04554a

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Cite this paper

@article{Yang2015EntrapmentOA, title={Entrapment of a chiral cobalt complex within silver: a novel heterogeneous catalyst for asymmetric carboxylation of benzyl bromides with CO2.}, author={Hengpan Yang and Ying-Na Yue and Qi-Long Sun and Qiu Feng and Huan Wang and Jia-Xing Lu}, journal={Chemical communications}, year={2015}, volume={51 61}, pages={12216-9} }