Enhancements of enantio and diastereoselectivities in reduction of (Z)-3-halo-4-phenyl-3-buten-2-one mediated by microorganisms in ionic liquid/water biphasic system

@inproceedings{Zampieri2013EnhancementsOE,
  title={Enhancements of enantio and diastereoselectivities in reduction of (Z)-3-halo-4-phenyl-3-buten-2-one mediated by microorganisms in ionic liquid/water biphasic system},
  author={D{\'a}vila S. Zampieri and Bruno Souza de Paula and Luiz Arthur Zampieri and Juliana A Vale and Jos{\'e} Augusto Ros{\'a}rio Rodrigues and Paulo Jos{\'e} Samenho Moran},
  year={2013}
}
Abstract Reductions of ( Z )-C 6 H 5 CH CXC( O)CH 3 (X = Cl, Br) mediated by Saccharomyces cerevisiae , Candida albicans , Rhodotorula glutinis , Geotrichum candidum and Micrococcus luteus gave the corresponding halohydrins through consecutive reduction reactions of C C and C O bonds. In general, the reactions performed in the biphasic system water/[(bmim)PF 6 ] gave better diastereoselectivity and enantioselectivity than in pure water. 

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