• DOI:10.1039/c2dt31346d
• Corpus ID: 2237120

Enhanced electronic correlation and thermoelectric response by Cu-doping in Ca3Co4O9 single crystals.

@article{Huang2012EnhancedEC,
  title={Enhanced electronic correlation and thermoelectric response by Cu-doping in Ca3Co4O9 single crystals.},
  author={Yanan Huang and Bangchuan Zhao and Xinbo Hu and Shuai Lin and Ran Ang and Wenhai Song and Yuping Sun},
  journal={Dalton transactions},
  year={2012},
  volume={41 36},
  pages={
          11176-86
        }
}

• Yanan Huang, Bangchuan Zhao, +4 authors Yuping Sun
• Published 28 August 2012
• Materials Science
• Dalton transactions

The structure, anisotropic magnetic, electrical and thermal transport properties for single crystals of Ca(3)Co(4-x)Cu(x)O(9) (x = 0, 0.2, 0.4, 0.6 and 0.8) have been investigated systematically. The Cu-doping with x = 0.2 at Co-site is sufficient to drive the low-temperature spin-glass state in the Ca(3)Co(4)O(9) system. The value of resistivity along ab-plane decreases monotonously with increasing x in the whole temperature range studied, and around room temperature, the in-plane resistivity of Ca(3)Co(3.2)Cu(0.8)O(9) is about 71% smaller than that of the undoped sample. The temperature region where the Fermi-liquid transport mechanism dominates becomes remarkably narrowed due to the Cu-doping while the electronic correlation in the system is enhanced. With further addition of Cu in the Ca(3)Co(4)O(9) system, the in-plane thermopower (S(ab)) increases slowly and the room-temperature S(ab) for Ca(3)Co(3.2)Cu(0.8)O(9) is about 17% larger than that of the undoped sample. As a result, the power factor along the ab-plane is enhanced by about 3.8 times compared to the undoped sample. The results are suggested to originate from the variations of carrier concentration and electronic correlation in this system via the different Cu-doping states: Cu(3+)/Cu(2+) (Cu(3+) major) into the CoO(2) layer for x ≤ 0.4, while Cu(2+)/Cu(3+) (Cu(2+) major) into the Ca(2)CoO(3) layers for x > 0.4.