Enhanced deep-red luminescence of tris(hexafluoroacetylacetonato)samarium(III) complex with phenanthroline in solution by control of ligand coordination.


The effect of solvent molecule on the emission properties of Sm(hfa)3(phen)2 (hfa = hexafluoroacetylacetonato, phen = phenanthoroline) was investigated using acetone, acetonitrile, and pyridine. 5G(5/2) --> 5H(9/2) transition intensities in pyridine were found to be larger than those in corresponding acetone and acetonitrile. The radiative rate constant in… (More)
DOI: 10.1021/jp075855d

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