Enhanced Piezoelectric Response in Hybrid Lead Halide Perovskite Thin Films via Interfacing with Ferroelectric PbZr0.2Ti0.8O3.

@article{Song2018EnhancedPR,
  title={Enhanced Piezoelectric Response in Hybrid Lead Halide Perovskite Thin Films via Interfacing with Ferroelectric PbZr0.2Ti0.8O3.},
  author={Jingfeng Song and Zhiyong Xiao and Bo Chen and Spencer Prockish and Xuegang Chen and Anil Kumar Rajapitamahuni and Le Zhang and Jinsong Huang and Xia Hong},
  journal={ACS applied materials \& interfaces},
  year={2018},
  volume={10 22},
  pages={
          19218-19225
        }
}
We report a more than 10-fold enhancement of the piezoelectric coefficient d33 of polycrystalline CH3NH3PbI3 (MAPbI3) films when interfacing them with ferroelectric PbZr0.2Ti0.8O3 (PZT). Piezoresponse force microscopy (PFM) studies reveal [Formula: see text] values of 0.3-0.4 pm/V for MAPbI3 deposited on Au, indium tin oxide, and SrTiO3 surfaces, with small phase angle fluctuating at length scales smaller than the grain size. In sharp contrast, on samples prepared on epitaxial PZT films, we… 
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