Enantiospecific approaches to bicyclic vibsanes: a ring-closing metathesis reaction-based strategy to functionalized bicyclo[4.3.1]decanes

@article{Srikrishna2008EnantiospecificAT,
  title={Enantiospecific approaches to bicyclic vibsanes: a ring-closing metathesis reaction-based strategy to functionalized bicyclo[4.3.1]decanes},
  author={A. Srikrishna and Vijendra H. Pardeshi and G. Satyanarayana},
  journal={Tetrahedron-asymmetry},
  year={2008},
  volume={19},
  pages={1984-1991}
}
  • A. Srikrishna, Vijendra H. Pardeshi, G. Satyanarayana
  • Published 2008
  • Chemistry
  • Tetrahedron-asymmetry
  • An enantiospecific synthesis of functionalized bicyclo[4.3.1]decane, the bicyclic core system present in some bi- and tricyclic vibsane diterpenoids, for example, vibsanin E, via an RCM reaction of 2,6-diallylcarvone derivatives is described. It has been further extended to the synthesis of tricyclo[6.4.1.01,5]tridecanes starting from 2,6,6-triallylcarvones. 
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