Corpus ID: 104653121

Enantioselective total syntheses of Teubrevin G and Teubrevin H and studies toward the Enantioselective Total Synthesis of Vinigrol

@inproceedings{Efremov2001EnantioselectiveTS,
  title={Enantioselective total syntheses of Teubrevin G and Teubrevin H and studies toward the Enantioselective Total Synthesis of Vinigrol},
  author={I. Efremov},
  year={2001}
}
Total syntheses o f teubrevin G and teubrevin H are described. The successflil approach to these novel diterpenoids involves a highly regiocontrolled [4+2] cycloaddition-fragmentation sequence as a novel and possibly general method to assemble functionalized monocyclic furans. Medium-sized ring construction was accomplished by efficient ring-closing olefin metathesis. Utilization o f a new generation ruthenium catalyst was shown to be crucial for the success o f this transformation. Two o f… Expand

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