Enantioselective stopped-flow multidimensional gas chromatography. Determination of the inversion barrier of 1-chloro-2,2-dimethylaziridine.

@article{Reich2000EnantioselectiveSM,
  title={Enantioselective stopped-flow multidimensional gas chromatography. Determination of the inversion barrier of 1-chloro-2,2-dimethylaziridine.},
  author={Shimon Reich and Oliver Trapp and Volker Schurig},
  journal={Journal of chromatography. A},
  year={2000},
  volume={892 1-2},
  pages={487-98}
}
Enantioselective stopped-flow multidimensional gas chromatography (stopped-flow MDGC) is a fast and simple technique to determine enantiomerization (inversion) barriers in the gas phase in a range of delta G#gas(T)=70-200 kJ mol(-1). After complete gas-chromatographic separation of the enantiomers in the first column, gas phase enantiomerization of the… CONTINUE READING