Enantioselective Rhodium-Catalyzed Alkenylation of Aliphatic Imines.

Abstract

An efficient, enantioselective rhodium-catalyzed addition of potassium alkenyltrifluoroborates to N-nosyl aliphatic imines has been realized. Good reaction yields and excellent enantioselectivities (94-99% ee) were obtained for a variety of aliphatic imines and nucleophilic alkenyltrifluoroborates. An active rhodium-diene catalyst and the precise reaction… (More)
DOI: 10.1021/acs.orglett.7b02737

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