Enantiomer identification in the flavour and fragrance fields by "interactive" combination of linear retention indices from enantioselective gas chromatography and mass spectrometry.

@article{Liberto2008EnantiomerII,
  title={Enantiomer identification in the flavour and fragrance fields by "interactive" combination of linear retention indices from enantioselective gas chromatography and mass spectrometry.},
  author={Erica Liberto and Cecilia Cagliero and Barbara Sgorbini and Carlo Alberto Antonio Bicchi and Danilo Sciarrone and Barbara D'Acampora Zellner and Luigi Mondello and Patrizia Rubiolo},
  journal={Journal of chromatography. A},
  year={2008},
  volume={1195 1-2},
  pages={
          117-26
        }
}
This study describes the development of a gas chromatography-mass spectrometry (GC-MS) library to identify optically active compounds in the flavour and fragrance field using enantioselective GC with cyclodextrin derivatives (CDs) as chiral selectors in combination with MS. The library operates on the "interactive" combination of linear retention indices (I(T) values) in parallel to MS spectra, so as to identify enantiomers reliably and to measure EE and/or ER unequivocally. Since MS is not a… CONTINUE READING

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