Electronic ground states of the trigonal-prismatic rhenium complexes, tris(cis-1,2-diphenylethene-1,2-dithiolato)rhenium, and tris(toluene-3,4-dithiolato)rhenium

@inproceedings{AlMowali1975ElectronicGS,
  title={Electronic ground states of the trigonal-prismatic rhenium complexes, tris(cis-1,2-diphenylethene-1,2-dithiolato)rhenium, and tris(toluene-3,4-dithiolato)rhenium},
  author={Ali H. Al-Mowali and Andrew L. Porte},
  year={1975}
}
  • Ali H. Al-Mowali, Andrew L. Porte
  • Published 1975
  • Chemistry
  • The electron paramagnetic resonance spectra of the trigonal prismatic complexes, [Re(S2C2Ph2)3] and [Re(tdt)3](tdt = toluene-3,4-dithiolate), are characteristic of sulphur-containing organic radicals and they show that the unpaired electron in these compounds is in a non-bonding molecular orbital derived from the ligand π orbitals, E.p.r. properties, visible-u.v. absorption spectra, voltammetric properties, the magnetic properties of ions derived from [Re(S2C2R2)3], and the unusually high… CONTINUE READING

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