Electronic effects in (salen)Mn-based epoxidation catalysts.

Abstract

Presented are density functional calculations on various Mn(salen) systems that are active catalysts in the epoxidation of olefins. Correlation of various structural properties such as Mn=O bond strengths, atomic charges, and C-O distances of evolving bonds in transition state geometries with modified Hammett constants reveal a mechanistic picture of the epoxidation reaction, supporting previous experimental results. Enantioselectivity is tied to the position of a transition state along the reaction coordinate for the first C-O bond formation step, when an olefin is approaching the epoxidation catalyst. Electronic effects exhibited by the 5,5' substituents of the salen ligand manifest themselves in a tuning of the Mn=O bond strength, which in turn influences the C-O distance of the forming bond in the transition state geometry.

8 Figures and Tables

Cite this paper

@article{Cavallo2003ElectronicEI, title={Electronic effects in (salen)Mn-based epoxidation catalysts.}, author={Luigi Cavallo and Heiko Jacobsen}, journal={The Journal of organic chemistry}, year={2003}, volume={68 16}, pages={6202-7} }