Electronic coupling between two cyclometalated ruthenium centers bridged by 1,3,6,8-tetrakis(1-butyl-1H-1,2,3-triazol-4-yl)pyrene.


A new bridging ligand 1,3,6,8-tetrakis(1-butyl-1H-1,2,3-triazol-4-yl)pyrene (ttapyr) was designed and synthesized by "click" chemistry. This ligand was used to construct a linear dimetallic biscyclometalated Ru(II) complex [(tpy)Ru(ttapyr)Ru(tpy)](2+) and a monometallic complex [(tpy)Ru(ttapyr)](+), where tpy is 2,2':6',2″-terpyridine. The electronic… (More)
DOI: 10.1021/ic2005776


Figures and Tables

Sorry, we couldn't extract any figures or tables for this paper.